Effect of cooling rate on microstructure of B2-NiSc intermetallics
Keywords:
centrifugal casting, B2-NiSc, microstructure evolution, rapid solidification, heat treatment, (Ni2Sc NiSc)eutecticAbstract
Ni-50at%Sc alloy was prepared by centrifugal
casting method. Volume fraction, the actual
content of B2-NiSc and second phase Ni2Sc in
alloy were analyzed with an Image-Pro Plus
software. The cooling rates for the solidified thin
plate with thickness of 2.65mm, 1.2mm, 0.75mm
and 0.35 mm are 1164, 2570, 4112 and 8811 K·s-
1, respectively. It is found that d=0.5 mm was an
critical dimension which corresponds to an abrupt
change in the solidification rate. It is also found
that (Ni2Sc+NiSc)eutectic was dispersed at grain
boundary or between dendritic arms due to the loss
of Sc element during melting. While d? 0.5mm
(corresponding to the thin plate with thickness of
0.75mm, 1.20mm and 2.65 mm), the solidification
structure consists of primary phase B2-NiSc and
(Ni2Sc+NiSc)eutectic. While d ? 0.5mm
(corresponding to the thin plate with thickness of
0.35 mm), the solidification structure is composed
of fine globular B2-NiSc and relatively small
amounts of (Ni2Sc+NiSc)eutectic. Based on the phase
volumetric analyzing of the microstructure with an
Image-Pro Plus software, the loss of Sc element
during melting was about 3.01~3.10 at%. The
eutectic NiSc in the lamellar eutectic structure
together with the primary phase B2-NiSc form a
larger single phase NiSc, while Ni2Sc with the form
of particles is distributed on the grain boundaries
after (970 ?, 72 h) homogenization heat
treatment.
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